| 17400 | Mendeleev focused on abstract elements, not simple substances, so he got to their essence [Mendeleev, by Scerri] |
| Full Idea: Because he was attempting to classify abstract elements, not simple substances, Mendeleev was not misled by nonessential chemical properties. | |
| From: report of Dmitri Mendeleev (The Principles of Chemistry [1870]) by Eric R. Scerri - The Periodic Table 04 'Making' | |
| A reaction: I'm not fully clear about this, but I take it that Mendeleev stood back from the messy observations, and tried to see the underlying simpler principles. 'Simple substances' were ones that had not so far been decomposed. |
| 17401 | Mendeleev had a view of elements which allowed him to overlook some conflicting observations [Mendeleev] |
| Full Idea: His view of elements allowed Mendeleev to maintain the validity of the periodic table even in instances where observational evidence seemed to point against it. | |
| From: Dmitri Mendeleev (The Principles of Chemistry [1870]), quoted by Eric R. Scerri - The Periodic Table 04 'Making' | |
| A reaction: Mendeleev seems to have focused on abstract essences of elements, rather than on the simplest substances they had so far managed to isolate. |
| 12450 | The periodic table not only defines the elements, but also excludes other possible elements [Azzouni] |
| Full Idea: The periodic table not only governs what elements there can be, with their properties, but also explicitly excludes others sorts of elements, because the elements are individuated by the number of discrete protons in their nuclei. | |
| From: Jody Azzouni (Deflating Existential Consequence [2004], Ch.7) | |
| A reaction: It has to be central to the thesis of scientific essentialism that the possibilities in nature are far more restricted than is normally thought, and this observation illustrates the view nicely. He makes a similar point about subatomic particles. |
| 17480 | Generally it is nuclear charge (not nuclear mass) which determines behaviour [Hendry] |
| Full Idea: In general, nuclear charge is the overwhelming determinant of an element's chemical behaviour, while nuclear mass is a negligible factor. | |
| From: Robin F. Hendry (Chemistry [2008], 'Micro') | |
| A reaction: The exception is the isotopes of very light elements light hydrogen. |
| 17395 | Elements were ordered by equivalent weight; later by atomic weight; finally by atomic number [Scerri] |
| Full Idea: Historically, the ordering of elements across periods was determined by equivalent weight, then later by atomic weight, and eventually by atomic number. | |
| From: Eric R. Scerri (The Periodic Table [2007], 01 'React') | |
| A reaction: So they used to be ordered by quantities (measured by real numbers), but eventually were ordered by unit items (counted by natural numbers). There need to be distinct protons (unified) to be counted. |
| 17410 | Moseley showed the elements progress in units, and thereby clearly identified the gaps [Scerri] |
| Full Idea: Moseley's work showed that the successive elements in the periodic table have an atomic number greater by one unit. The gaps could then be identified definitively, as 43, 61, 72, 75, 85, 87, and 91. | |
| From: Eric R. Scerri (The Periodic Table [2007], 06 'Henry') | |
| A reaction: [compressed] |
| 17406 | Moseley, using X-rays, showed that atomic number ordered better than atomic weight [Scerri] |
| Full Idea: By using X-rays, Henry Moseley later discovered that a better ordering principle for the periodic system is atomic numbers rather than atomic weight, by subjecting many different elements to bombardment. | |
| From: Eric R. Scerri (The Periodic Table [2007], 06 'Intro') | |
| A reaction: Moseley was killed in the First World War at the age of 26. It is interesting that they more or less worked out the whole table, before they discovered the best principle on which to found it. |
| 17408 | Some suggested basing the new periodic table on isotopes, not elements [Scerri] |
| Full Idea: Some chemists even suggested that the periodic table would have to be abandoned in favor of a classification system that included a separate place for every single isotope. | |
| From: Eric R. Scerri (The Periodic Table [2007], 06 'Intro') | |
| A reaction: The extreme case is tin, which has 21 isotopes, so is tin a fundamental, or is each of the isotopes a fundamental? Does there have to be a right answer to that? All tin isotopes basically react in the same way, so we stick with the elements table. |
| 17412 | Elements are placed in the table by the number of positive charges - the atomic number [Scerri] |
| Full Idea: The serial number of an element in the periodic table, its atomic number, corresponds to the number of positive charges in the atom. | |
| From: Eric R. Scerri (The Periodic Table [2007], 07 'Models') | |
| A reaction: Note that this is a feature of the nucleus, despite that fact that the electrons decide the chemical properties. A nice model for Locke's views on essentialism. |
| 17414 | Pauli explained the electron shells, but not the lengths of the periods in the table [Scerri] |
| Full Idea: Pauli explained the maximum number of electrons successive shells can accommodate, ...but it does not explain the lengths of the periods, which is the really crucial property of the periodic table. | |
| From: Eric R. Scerri (The Periodic Table [2007], 07 'Pauli') | |
| A reaction: Paulis' Exclusion Principle says no two electrons in an atom can have the same set of four quantum numbers. He added 'spin' as a fourth number. It means 'electrons cannot be distinguished' (243). Scerri says the big problem is still not fully explained. |
| 17413 | Elements in the table are grouped by having the same number of outer-shell electrons [Scerri] |
| Full Idea: The modern notion is that atoms fall into the same group of the periodic table if they possess the same numbers of outer-shell electrons. | |
| From: Eric R. Scerri (The Periodic Table [2007], 07 'Quantum') | |
| A reaction: Scerri goes on to raise questions about this, on p.242. By this principle helium should be an alkaline earth element, but it isn't. |
| 17416 | Orthodoxy says the periodic table is explained by quantum mechanics [Scerri] |
| Full Idea: The prevailing reductionist climate implies that quantum mechanics inevitably provides a more fundamental explanation for the periodic system. | |
| From: Eric R. Scerri (The Periodic Table [2007], 08 'Concl') | |
| A reaction: Scerri has argued that chemists did much better than physicists in working out how the outer electron shells of atoms worked, by induction from data, rather than inference from basic principles. |
| 17417 | To explain the table, quantum mechanics still needs to explain order of shell filling [Scerri] |
| Full Idea: The order of shell filling has not yet been deduced from first principles, and this issue cannot be avoided if one is to really ask whether quantum mechanics explains the periodic system in a fundamental manner. | |
| From: Eric R. Scerri (The Periodic Table [2007], 09 'From') |
| 17419 | Since 99.96% of the universe is hydrogen and helium, the periodic table hardly matters [Scerri] |
| Full Idea: All the elements other than hydrogen and helium make up just 0.04% of the universe. Seen from this perspective, the periodic table appears to rather insignificant. | |
| From: Eric R. Scerri (The Periodic Table [2007], 10 'Astro') |
| 17422 | The best classification needs the deepest and most general principles of the atoms [Scerri] |
| Full Idea: An optimal classification can be obtained by identifying the deepest and most general principles that govern the atoms of the elements. | |
| From: Eric R. Scerri (The Periodic Table [2007], 10 'Continuum') | |
| A reaction: He adds (p.286) that the best system will add the 'greatest degree of regularity' to these best principles. |
| 17466 | Mendeleev systematised the elements, and also gave an account of their nature [Weisberg/Needham/Hendry] |
| Full Idea: In addition to providing the systematization of the elements used in modern chemistry, Mendeleev also gave an account of the nature of the elements which informs contemporary philosophical understanding. | |
| From: Weisberg/Needham/Hendry (Philosophy of Chemistry [2011], 1.3) |
| 17603 | Chemistry just needs the periodic table, and protons, electrons and neutrinos [New Sci.] |
| Full Idea: Ei-ichi Negishi (Nobel chemist of 2010) says 'I work with the periodic table in front of me at all times, and approach all challenges in terms of three particles, positively charged protons, negatively charged electrons, and neutral neutrinos'. | |
| From: New Scientist writers (New Scientist articles [2013], 2010.10.16) |