| 23185 | In chemistry every substance pushes, and thus creates new substances [Nietzsche] |
| Full Idea: In chemistry is revealed that every substance pushes its force as far as it can, then a third something emerges. | |
| From: Friedrich Nietzsche (Unpublished Notebooks 1885-86 [1886], 34[51]) | |
| A reaction: This is the ontology of powers as the basis of science, of which I am a fan. It is Nietzsche's Will to Power in action, which is often mistakenly taken to only refer to human affairs. |
| 15259 | Chemical atoms have two powers: to enter certain combinations, and to emit a particular spectrum [Harré/Madden] |
| Full Idea: The same electronic constitution confers two distinct powers upon chemical atoms: the power of entering only into certain chemical combinations and the power to radiate a particular spectrum. | |
| From: Harré,R./Madden,E.H. (Causal Powers [1975], 5.VI) | |
| A reaction: Presumably radioactive elements emit other radiation. Do atoms have passive powers as well as active ones? |
| 15263 | Chemistry is not purely structural; CO2 is not the same as SO2 [Harré/Madden] |
| Full Idea: Modern chemistry is not, as chemistry, purely structural. ...Thus CO2 is a different substance from SO2. | |
| From: Harré,R./Madden,E.H. (Causal Powers [1975], 6.II) | |
| A reaction: I don't think I ever thought the chemistry was purely structural, but if you go in for the idea that reality is essentially geometrical (inspired by physics, presumably, like Ladyman) then you might make this mistake. |
| 14098 | An acid is just a proton donor [Rosen] |
| Full Idea: To be an acid just is to be a proton donor. | |
| From: Gideon Rosen (Metaphysical Dependence [2010], 10) | |
| A reaction: My interest here is in whether we can say that we have found the 'essence' of an acid - so we want to know whether something 'deeper' explains the proton-donation. I suspect not. Being a proton donor happens to have a group of related consequences. |
| 20651 | The shape of molecules is important, as well as the atoms and their bonds [Watson] |
| Full Idea: Pauling showed that the architecture - the shape of molecules was relevant (as well as the bonds). This meant that molecules were just as important as atoms in the understanding of matter. Molecules were not just the sum of their parts. | |
| From: Peter Watson (Convergence [2016], 05 'Three') | |
| A reaction: If Aristotle struggled to understand matter, then so should modern philosophers. This involves thermodynamics and chemistry, as well as quantum theory. |
| 17482 | Compounds can differ with the same collection of atoms, so structure matters too [Hendry] |
| Full Idea: The distinctness of the isomers ethanol (CH3CH2OH, boiling at 78.4°) and dimethyl ether (CH3OCH3, boiling at -24.9°) must lie in their different molecular structures. ...But structure has continuously varying quantities, like bond length and angle. | |
| From: Robin F. Hendry (Chemistry [2008], 'Micro') | |
| A reaction: [compressed] This seems to imply that what matters is an idealised abstraction of the structure (i.e. its topology), which is a reason for denying that chemistry is reducible to mere physics. |
| 17483 | Water continuously changes, with new groupings of molecules [Hendry] |
| Full Idea: Macroscopic bodies of water are complex and dynamic congeries of different molecular species, in which there is a constant dissociation of individual molecules, re-association of ions, and formation, growth and disassociation of oligomers. | |
| From: Robin F. Hendry (Chemistry [2008], 'Micro') | |
| A reaction: The point is that these activities are needed to explain the behaviour of water (such as its conductivity). |
| 17392 | How can poisonous elements survive in the nutritious compound they compose? [Scerri] |
| Full Idea: A central mystery of chemistry is how the elements survive in the compounds they form. For example, how can poisonous grey metal sodium combine with green poisonous gas chlorine, to make salt, which is non-poisonous and essential for life? | |
| From: Eric R. Scerri (The Periodic Table [2007], Intro 'Elem') | |
| A reaction: A very nice question which had never occurred to me. If our digestive system pulled the sodium apart from the chlorine, we would die. |
| 17391 | Periodicity and bonding are the two big ideas in chemistry [Scerri] |
| Full Idea: The two big ideas in chemistry are chemical periodicity and chemical bonding, and they are deeply interconnected. | |
| From: Eric R. Scerri (The Periodic Table [2007], Intro 'Per') |
| 17404 | Chemistry does not work from general principles, but by careful induction from large amounts of data [Scerri] |
| Full Idea: Unlike in physics, chemical reasoning does not generally proceed unambiguously from general principles. It is a more inductive science in which large amounts of observational data must be carefully weighed. | |
| From: Eric R. Scerri (The Periodic Table [2007], 05 'Mendel') | |
| A reaction: This is why essentialist thinking was important for Mendeleev, because it kept his focus on the core facts beneath the messy and incomplete data. |
| 17407 | The electron is the main source of chemical properties [Scerri] |
| Full Idea: It is the electron that is mainly responsible for the chemical properties of the elements. | |
| From: Eric R. Scerri (The Periodic Table [2007], 06 'Intro') |
| 17409 | Does radioactivity show that only physics can explain chemistry? [Scerri] |
| Full Idea: Some authors believe that the interpretation of the properties of the elements passed from chemistry to physics as a result of the discovery of radioactivity. ...I believe this view to be overly reductionist. | |
| From: Eric R. Scerri (The Periodic Table [2007], 06 'Radio') | |
| A reaction: It is all a matter of the explanations, and how far down they have to go. If most non-radiocative chemistry doesn't need to mention the physics, then chemistry is largely autonomous. |
| 17415 | A big chemistry idea is that covalent bonds are shared electrons, not transfer of electrons [Scerri] |
| Full Idea: One of the most influential ideas in modern chemistry is of a covalent bond as a shared pair of electrons (not as transfer of electrons and the formation of ionic bonds). | |
| From: Eric R. Scerri (The Periodic Table [2007], 08 'Intro') | |
| A reaction: Gilbert Newton Lewis was responsible for this. |
| 17468 | Over 100,000,000 compounds have been discovered or synthesised [Weisberg/Needham/Hendry] |
| Full Idea: There are well over 100,000,000 chemical compounds that have been discovered or synthesised, all of which have been formally characterised. | |
| From: Weisberg/Needham/Hendry (Philosophy of Chemistry [2011], 4.3) |
| 17469 | 'H2O' just gives the element proportions, not the microstructure [Weisberg/Needham/Hendry] |
| Full Idea: 'H2O' is not a description of any microstructure. It is a compositional formula, describing the combining proportions of hydrogen and oxygen to make water. | |
| From: Weisberg/Needham/Hendry (Philosophy of Chemistry [2011], 4.5) |
| 17470 | Water molecules dissociate, and form large polymers, explaining its properties [Weisberg/Needham/Hendry] |
| Full Idea: Water's structure cannot simply be described as a collection of individual molecules. There is a continual dissociation of H2O molecules into hydrogen and hydroxide ions; they former larger polymeric species, explaining conductivity, melting and boiling. | |
| From: Weisberg/Needham/Hendry (Philosophy of Chemistry [2011], 4.5) | |
| A reaction: [compressed] If philosophers try to state the 'essence of water', they had better not be too glib about it. |
| 17473 | It is unlikely that chemistry will ever be reduced to physics [Weisberg/Needham/Hendry] |
| Full Idea: Most philosophers believe chemistry has not been reduced to physics nor is it likely to be. | |
| From: Weisberg/Needham/Hendry (Philosophy of Chemistry [2011], 6) | |
| A reaction: [Le Poidevin 2007 argues the opposite] That chemical features are actually metaphysically 'emergent' is a rare view, defended by Hendry. The general view is that the concepts are too different, and approximations render it hopeless. |
| 17474 | Quantum theory won't tell us which structure a set of atoms will form [Weisberg/Needham/Hendry] |
| Full Idea: Quantum mechanics cannot tell us why a given collection of atoms will adopt one molecular structure (and set of chemical properties) or the other. | |
| From: Weisberg/Needham/Hendry (Philosophy of Chemistry [2011], 6.1) | |
| A reaction: Presumably it the 'chance' process of how the atoms are thrown together. |
| 17475 | For temperature to be mean kinetic energy, a state of equilibrium is also required [Weisberg/Needham/Hendry] |
| Full Idea: Having a particular average kinetic energy is only a necessary condition for having a given temperature, not a sufficient one, because only gases at equilibrium have a well-defined temperature. | |
| From: Weisberg/Needham/Hendry (Philosophy of Chemistry [2011], 6.2) | |
| A reaction: If you try to pin it all down more precisely, the definition turns out to be circular. |
| 17604 | We are halfway to synthesising any molecule we want [New Sci.] |
| Full Idea: Ei-ichi Negishi (Nobel chemist of 2010) says 'the ultimate goal is to be able to synthesise any molecule we want. We are probably about halfway there'. | |
| From: New Scientist writers (New Scientist articles [2013], 2010.10.16) |